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https://www.theartist.me/art-movement/paleolithic-art/
Painting in the Paleolithic era was done with various tools and mediums. Some artists daubed or stippled with moss or fur, others used their finger or sticks in the way that we use brushed, and others used colored rocks, chalks, and charcoal to draw.
https://courses.lumenlearning.com/boundless-arthistory/chapter/the-paleolithic-period/
The artists used polychromy—charcoal and ochre or haematite—to create the images, often diluting these pigments to produce variations in intensity , creating an impression of chiaroscuro . They also exploited the natural contours in the cave walls to give their subjects a three-dimensional effect.
http://www.visual-arts-cork.com/artist-paints/prehistoric-colour-palette.htm
Pigments Used in Ancient African Art The prehistoric colour palette used in African cave painting by Bushmen artists consisted mostly of earth pigments. Reds and browns from bole or haematite; yellows, orange and reds from ochre; white from zinc oxide; blue from iron and silicic acid; blacks from charcoal or …
http://www.webexhibits.org/pigments/intro/early.html
The palette Prehistoric painters used the pigments available in the vicinity. These pigments were the so-called earth pigments, (minerals limonite and hematite, red ochre, yellow ochre and umber), charcoal from the fire (carbon black), burnt bones (bone black) and white from grounded calcite (lime white).
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